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The early K-type T-Tauri star, V1298 Tau (V= 10 mag, age ≈ 20–30 Myr) hosts four transiting planets with radii ranging from 4.9 to 9.6R_⊕. The three inner planets have orbital periods of ≈8–24 days while the outer planet’s period is poorly constrained by single transits observed with K2 and the Transiting Exoplanet Survey Satellite (TESS). Planets b, c, and d are proto–sub-Neptunes that may be undergoing significant mass loss. Depending on the stellar activity and planet masses, they are expected to evolve into super-Earths/sub-Neptunes that bound the radius valley. Here we present results of a joint transit and radial velocity (RV) modeling analysis, which includes recently obtained TESS photometry and MAROON-X RV measurements. Assuming circular orbits, we obtain a low-significance (≈2σ) RV detection of planet c, implying a mass of${19.8}_{-8.9}^{+9.3}{M}_{\oplus }$and a conservative 2σupper limit of <39M_⊕. For planets b and d, we derive 2σupper limits ofM_b< 159M_⊕andM_d< 41M_⊕, respectively. For planet e, plausible discrete periods ofP_e> 55.4 days are ruled out at the 3σlevel while seven solutions with 43.3 <P_e/d< 55.4 are consistent with the most probable 46.768131 ± 000076 days solution within 3σ. Adopting the most probable solution yields a 2.6σRV detection with a mass of 0.66 ± 0.26M_Jup. Comparing the updated mass and radius constraints with planetary evolution and interior structure models shows that planets b, d, and e are consistent with predictions for young gas-rich planets and that planet c is consistent with having a water-rich core with a substantial (∼5% by mass) H₂envelope.

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability¹. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program^2,3found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO₂) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M_J) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. ⁴). The most plausible way of generating SO₂in such an atmosphere is through photochemical processes^5,6. Here we show that the SO₂distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations⁷with NIRSpec PRISM (2.7σ)⁸and G395H (4.5σ)⁹. SO₂is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H₂S) is destroyed. The sensitivity of the SO₂feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO₂also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.